![]() ![]() We discuss how our results complement and extend recent findings on the crystallization of ZIF-8 with SOD topology under similar synthetic conditions. The reaction kinetics speeds up with increasing linker-to-metal concentration ratio, yielding nanocrystals with decreasing size, while the life times of amorphous intermediates become very short and challenging to be observed experimentally. The latter particles transform into the periodic ZIF-71 structure with RHO topology, probably via intraparticle nucleation and subsequent particle reorganization. By taking advantage of the combined use of time-resolved static and dynamic light scattering and stopped-flow synchrotron small-angle and wide-angle X-ray scattering, we were able to reveal the whole nanocrystal formation process: a population of small amorphous particles (termed clusters) first forms via coagulation, followed by the formation of a second population of bigger amorphous particles that grow via addition of significantly smaller "monomers", the nature of which remains as yet unknown (clusters and/or smaller units). In a dynamic light scattering measurement, the time-dependent fluctuations in the scattered light are measured by a fast photon counter. In this contribution, we present the results of in situ studies on a recently developed fast ZIF-71 nanocrystal synthesis from solution. Information such as size, molecular weight, diffusion and interaction strength are obtained. But, the number of particles analyzed by AFM is much smaller, consequently, DLS offers an improved size distribution. Dynamic light scattering (DLS), also known as photon correlation spectroscopy (PCS), is a commonly used characterization method for nanoparticles. The current rather poor understanding of the mechanisms of crystallization of zeolitic imidazolate frameworks (ZIFs), an important subclass of porous metal organic framework (MOF) materials, greatly hampers rational synthesis of predicted ZIF phases/polymorphs and control of crystal size/shape. Static and Dynamic Light Scattering (SLS/DLS) Light scattering is a well established technique to investigate properties of particles in solutions.
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![]() Once Steam finished the synchronization, the last step you have to do is launch the game and enjoy the free level and rewards. Just click continue and Steam will handle the rest. Steam will give you several options but you should select the Upload from local option. You will receive a message that your game files are out of sync. Now that you have renamed the save file, open the game directly on Steam. Engine Stand Mod: New modifications for Car Mechanic Simulator 2021 will allow you to rotate the engine rack freely. To use the code, simply rename the file with the desired codes above. Go to the save game folder of Car Mechanic Simulator 2 and find the file with a name similar to the one that you created in the game. Car Mechanic Simulator 2021 is a new production with a well-established player base. By default, you can found it in your AppData folder. Let say you want to reach level 59 and get the free $500,000 cash, then you have to use cms2021promo as your name.īut what if you already have your profile created? Fortunately, there’s still a way to get the codes above.Īll you have to do is go to the directory of Car Mechanic Simulator 2021 game files. To use the available codes above, you have to create a new profile and use the codes as your name to get the rewards. How to Use Car Mechanic Simulator 2021 Codes Car Mechanic Simulator 2021 Codes Codesīring you to Level 31 and free $4,000 cash.īring you to Level 59 and free $500,000 cash. Of course, this is optional and you can use it anytime you want as these codes are non-expiring codes. Within you will find the complete list of working Car Mechanic Simulator 2021 codes that will give you free XP and money. Similar to the previous game installment, the developer has prepared some cheat codes that you can use if you don’t want to waste your time grinding or simply just want to test out some car parts. The game makes its successful launch last August 11th and the fanbase has already started growing since its release. Car Mechanic Simulator 2021 is the newest simulation game developed by Red Dot Games. The company has a strong focus on innovation and technology, which has helped them create some of the most advanced electric bikes on the market. Himiway is a leading name in the electric bike industry, with a wide range of products that cater to riders of all levels. However, because it is not an electric mountain bike, it is not as well-suited for off-road riding as the Himiway Bike. It has a smaller motor that is more efficient, and its tires are narrower, which makes it more aerodynamic. The Rad Rover, on the other hand, is perfect for those who want to use their electric bike for commuting or long-distance riding. However, because it is an electric mountain bike, it is not as well-suited for long-distance riding as the Rad Rover. It has a powerful motor that can take on any terrain, and its fat tires provide extra stability and traction. The Himiway Bike is perfect for those who want to take their electric bike off-road. The main difference between the Himiway Bike and the Rad Rover is that the former is an electric mountain bike while the latter is a fat tire electric bike.īoth of these types of bikes have their own set of pros and cons that make them ideal for different types of riders. ![]() ![]() It can be hard to decide which brand is right for you, but in this Himiway bike vs Rad Power Bikes comparison, we’ll take a close look at both brands and help you choose the best option for your needs. Both offer a wide range of models to suit different needs and budgets.Īnd while they share some similarities, there are also some key differences between them. Himiway and Rad Power Bikes are two of the most popular electric bike brands on the market. The states with the lowest income tax rates are a mix of flat tax and graduated tax rates: North Dakota (2.9% top marginal tax rate), Pennsylvania (3.07% flat tax rate), and Indiana (3.23% flat tax rate). The states with the highest income tax rates all have graduated tax rates: California (13.30% top marginal tax rate), Hawaii (11% top marginal tax rate), New York (10.9% top marginal tax rate). States with a graduated tax rate collect progressively higher portions of residents' income as their earnings level increases.States with a flat tax rate collect the same percentage of income from everyone, regardless of how much they earn.And there are two different ways to impose them: flat tax rates and graduated (also known as progressive) tax rates. How states tax their residents' incomesĪmong the states that do assess personal income taxes, the rates vary widely from one to the next. New Hampshire doesn't tax W-2 income, and its levy on investment income is being phased out in 1 percentage point increments each year until it's fully repealed for tax years after 2026. But that tax was repealed starting in the 2021 tax year. ![]() Until recently, Tennessee only taxed income from investment earnings on bonds and stock, not income earned at a job. ![]() You won't have to pay any state income tax in Alaska, Florida, Nevada, South Dakota, Texas, Washington, or Wyoming. While people across the United States pay federal income taxes, depending on where you live, you may also be subject to state income taxes. By clicking ‘Sign up’, you agree to receive marketing emails from InsiderĪs well as other partner offers and accept our ![]() With so many types of antifreeze out there, it’s hard to predict exactly how long the coolant that’s in your car will maintain top-notch cold weather protection. Traditionally, this has been done with phosphates and silicates, otherwise known as inorganic oxides (typically giving antifreeze a green tinge), but inorganic oxides and something called ‘organic additive technology’ are more and more often used in their place, resulting in a wider spectrum of coolant colors.Įach of these additives forms a protective coating over the inside of the cooling system itself, and over time that layer can no longer be replenished, ‘wearing out’ the antifreeze and requiring that it be replaced. Preventing corrosion inside your engine’s water channels, as well as its water pump, thermostat, and radiator, is just as important to the longevity of your car as keeping things cool, which means antifreeze manufacturers have to include various additives in order to take into account minerals, scale, and rust. ![]() If antifreeze was just made up of glycol and water it would never really wear out – but there’s more to it than that. In a similar way, it also boosts the boiling point of water, providing protection at both ends of the spectrum, and outperforming pure water when dealing with environmental extremes. In a 50/50 mix, you’re looking at a mixture that can go down to nearly -50 degrees F before crystallization starts to occur. ![]() What’s interesting about ethylene glycol is that it’s only when mixed with water that it gains its amazing ability to resist freezing. The most common ratios used are 70 percent water to 30 percent antifreeze for very warm parts of the country, but in colder areas a safer ratio – and the one most manufacturers recommend – is 50:50 antifreeze to water. This is especially true during the winter months, when your engine is most vulnerable to the cold.Īntifreeze makes use of ethylene glycol which is mixed with water in order to both help cool your engine and resist freezing. It’s not a ‘set it and forget it’ situation however – antifreeze needs to be periodically inspected, and replaced, as the grind of daily driving takes its toll on the additives that keep your motor running smoothly. ![]() Where does ‘antifreeze’ come in? Given that coolant needs to stay liquid in order to do its job, not to mention avoid cracking the engine block open if it were to turn to ice after sitting overnight at well below freezing temperatures, in most climates you can’t simply poor water into your vehicle’s radiator and call it day.ĭecades of research have lead to antifreeze/coolant that resists low temperatures while also fighting corrosion and wear inside the cooling system itself. At its most basic, this is accomplished by running coolant through channels in the engine block with its flow regulated by a thermostat and a pump, and its temperature kept under control by a radiator at the front of the car or truck. Simply put, your automobile’s engine runs hot, and it requires a cooling system to keep it at its optimum operating temperature, regardless of whether you’re driving in the dead of winter or during the dog days of summer. The word ‘antifreeze’ is one of the most straightforward terms in the automotive lexicon. ![]() # Install prerequisitesīrew install ccache git git-lfs cmake python clang-format flex bison Please ensure Homebrew has been installed, and install a full copy of Xcode 12 or newer (not just the Xcode command-line tools, although you need to install those too - launch Xcode after installing or upgrading, and complete its installation of the "additional components" when prompted). The initial directory is assumed to be /Users/ Step 1: Install macOS prerequisites ![]() Osquery from source on macOS now requires 10.15 Catalina or newer. The current build of osquery supports deployment to the same set of macOS versions (macOS 10.14 and newer). j10 # where 10 is the number of parallel build jobs Sudo tar xvf osquery-toolchain-1.1.0-$.tar.gz -C /usr/local -strip 1Ĭmake -DOSQUERY_TOOLCHAIN_SYSROOT=/usr/local/osquery-toolchain. # Download and install the osquery toolchainĮxport ARCH=$(uname -m) # There is toolchain support for x86_64 and aarch64. Sudo apt install -no-install-recommends rpm binutils # Optional: install RPM packaging prerequisites Pip3 install timeout_decorator thrift=0.11.0 osquery pexpect=3.3 Sudo apt install -no-install-recommends python3-pip python3-setuptools python3-psutil python3-six python3-wheel # Optional: install python tests prerequisites Sudo apt install -no-install-recommends git python3 bison flex make The initial directory is assumed to be /home/. Note: the recommended system memory for building osquery is at least 8GB, or Clang may crash during the compilation of third-party dependencies. The build type is chosen when building on Windows, through the -config option, not during the configure phase. The default build type is RelWithDebInfo (optimizations active + debug symbols) and can be changed in the CMake configure phase by setting the CMAKE_BUILD_TYPE flag to Release or Debug. The rest of the dependencies are downloaded by CMake. The supported compilers are: the osquery toolchain (LLVM/Clang 9.0.1) on Linux, MSVC v142 on Windows, and AppleClang from Xcode Command Line Tools 11.7. While osquery runs on a large number of operating systems, we only provide build instructions for a select few. Osquery supports many flavors of Linux, macOS, and Windows. Preparing to build the osquery-packaging repository.Step 2: Download and build source on Windows.Optional: Install Python tests prerequisites.Features Requiring Special Build Entitlements.Step 2: Download and build source on macOS. ![]() Add built-in sound effects or record real-time voiceoverĪnother excellent InShot for PC is OpenShot Video Editor.A wide range of video formats supported.Overall, it is difficult to find a better video editor than iMovie on the Mac. The biggest highlight of iMovie is that all your projects will be stored in Apple’s cloud, which means you can interactively edit the same video file on your iPhone, iPad, and Mac. With iMovie, you can browse through clips, create Hollywood-style trailers, and even process 4K videos to get amazing movie-quality videos. It has a simple drag-and-drop function and supports multiple video formats. Besides, professionals can also use advanced options to optimize their videos. First of all, it has an intuitive interface, which is easy to use for novices. It is undoubtedly the most popular video editing software on the Mac. The first InShot for Mac on our list is iMovie. Apply picture-in-picture effect or split-screen effect.Lots of popular video filters and transitions.VSDC Pro allows you to use motion tracking, work with audio waveform, mask videos, stabilize shaky footage, record real-time voiceovers, apply multi-color chroma keys, etc. If you need more advanced tools, just upgrade them to the Pro version. And you can convert your video files to other formats. Thanks to its extensive format support, you can easily handle all popular media files. VSDC is a non-linear video editor, which means you can freely place video clips in the timeline. It has various functions for you to enhance your video quality. The software aims to provide users with a smooth editing experience, so even beginners can enjoy creative media projects. VSDC Free Video Editor is also a great InShot alternative. Multi-camera editing and 360° video editing.Speed up, slow down, and reverse videos.Apply lens corrections to remove fisheye distortion.Drag-and-drop overlays, titles, graphics, and transitions. ![]() Tons of templates, filters, and effects.In addition, you can import multiple formats for the source clip, and then export the video to various output formats. Using its excellent editing tools, you can turn every video into a Hollywood blockbuster.Īfter mastering the basics, you will find some more powerful features, including motion tracking, 4K support, 360-degree video support, multi-camera support, etc. In just 3 simple steps, you can turn any image into a fascinating animation. This powerful video editor has a very clear and intuitive interface that makes it easy to get started. More importantly, it has almost all the functions of other products in this list. It is a convenient and feature-rich video editor that can help you easily complete various editing tasks. Create a video with text, music, and 3D effectsĪnother alternative to InShot for PC is Corel VideoStudio.This program is an option best suited for beginners. You can easily perform tasks such as trimming the clips, adding music, applying visual effects, combine photos and videos into a single file instantly, etc. However, you’d better not expect too much because it doesn’t have a timeline and its video editing tools are limited to the essentials. The main benefit of using Photos is that it doesn’t cost you anything and is pretty lightweight. It is the app you can use to view media, both still and animated, as well as make edits to various supported file types. The next desktop alternative to InShot is Microsoft Photos. Tons of transitions, effects, and motions.After finishing all the editing, you can change the format of your video file to make it playable on more devices and media players, and you can even extract the audio track from the video. Most importantly, this free program allows you to change the video resolution and video format. Through its intuitive user interface and simple timeline, you can easily trim video, split video, rotate video, flip video, reverse video, change video speed, and add transitions, effects, motions, text as well as music to your video. It is a free and safe video making and editing program that provides you with all the tools you need, and it supports a wide range of image, audio, and video file formats. If you are looking for InShot for Windows, MiniTool MovieMaker is your first choice. The app has all the basic editing tools to help you easily create videos, edit videos from YouTube, Instagram, Facebook, Twitter, TikTok, Whatsapp, etc. InShot is a simple and powerful video editor and video production application that can be used on Android and iOS platforms. ![]() You should restart your console if this does not cure the problem. Simply plug the other end of the cable into a USB port on your console, then press and hold the Xbox button on your controller for a few seconds. If you can’t couple your controller with the buttons, try using a USB cord. Why isn’t my Xbox controller connecting?.Select Accessories from the Devices & Connections menu. Select Settings from the Profile & System menu. If your controller connects using a USB cable but loses connection after removing the cable, reconnect the cable and check for an update for your controller: To access the instructions, press the Xbox button. Check for any interfering items or equipment and, if necessary, move or unplug them. ![]() To fix the problem, consider updating your Xbox One controller and console. Whether your Xbox controller will not connect, check to see if the batteries are dead. It will say “Xbox Wireless Controller.” You can detach the cord and use the controller wirelessly once the synchronization is complete. Under “Add Bluetooth or other Device,” choose Bluetooth. It will say “Xbox Wireless Controller.” Wait until the Guide button turns solid white and the Bluetooth menu confirms the controller is connected before proceeding.Ĭonnect the other end of the cord to your controller after plugging it into a USB port on the Xbox. In your system tray, right-click the Bluetooth icon. The connection is successful if both the controller and receiver lights are always on. HOW TO CONNECTĬonnect the receiver to the host’s USB port the receiver’s light flashes then click the HOME button on the controller the controller’s light flashes. You can begin playing the game once the USB port is connected to the computer. The wire length has been extended to 7.2 feet! You can enjoy the game by sitting a little further away from the console. All of the buttons are meant to fit your hand pleasantly for lengthy hours of gameplay, and the grips and contours have been engineered to fit your hands more comfortably. Two electric motors built within the game make each impact, crash, and explosion more exciting and realistic, allowing gamers to feel the Rumble in their hands. The upgraded controller’s instruction execution system and chip provide excellent sensitivity and quick response. Stay in complete control with an 8-way directional pad and two analogue pressure-point triggers. ![]() Granted, they do have a mean bite and scorpion-like stinging tail, but they aren't usually hostile to adventurers, so that's a definite plus. So, unless you're downright evil, these fey creatures are great to hang around with and watch fly around the forest.Ī pocket-sized dragonic creature? Why wouldn't these things be cute? Sprites also have heart sense which lets them see a creature's emotional state. While they are deadly warriors when they need to be, they often avoid conflict. They're also neutral good, so they shouldn't bother you unless you are disrupting them or the sacred nature they often protect. These tiny fey humanoids are quite reminiscent of fairies from myth. ![]() Pretty much D&D's deadly equivalent of that "pet rock" toy. Speaking of friend shaped, these cubic creatures may not have a face or be able to communicate, but there is something about them that is oddly cute.Ī creature from early on in the creation of D&D, these classic monsters are made of a pudding-like acid that suffocates and then eats away at whatever was unlucky enough get stuck inside of it. They can get rather large, but the little ones definitely could get some "a8 Gelatinous Cube Like a cross between a shark and a puppy, these monsters can dive into the earth before leaping out and grabbing unsuspecting adventurers.īut, once again they look like an odd mix between a shark and a puppy. Maybe adore them from afar if you find your party in Mechanus. Lawfully Neutral, Monodrones or their more advanced duodrone and tridrone cousins shouldn't bother you unless you directly bother them. With their little wings and huge eyes, there is something rather weirdly cute about them. But, they do look like a steampunk Mike Wazowski. Whether it be a wintry fight on the foredeck of a galley or a foray into the feywilds gone bad, D&D has a handful of monsters perfect for the situation.īut, what of the monsters that aren't horrific or gruesome? What of the furry ones that make you want to hug them, or at least the weird ones that are just too unique to not "aww" at? Whether you want to throw a cute monster at the party as a potential companion or you want to horrify them as a cuddly encounter turns deadly, here are some of the cutest monsters in D&D.įiercely loyal to their own society in the plane of Mechanus and having limited intelligence, these creatures aren't to be messed with. ![]() Some are strong, some terrifying, and some are downright adorable.ĭungeons and Dragons has a menagerie of different monsters and enemies for any occasion you could think of. 10 Cutest Dungeons & Dragons Monsters,Dungeons and Dragons has a wide range of monsters for you to encounter. |